9-Borabicyclo [3.3.1]nonane, a commercially available reagent, is the most versatile hydroborating reagent to synthesize organoboranes (B-R-9-BBN). The reagent exhibits remarkable regio-, chemo-, and stereoselectivity during hydroboration reactions. The organoboranes can be converted to C-H, C-O, C-N, C-S, C-halogen, C-metal and above all C-C bonds. In addition, the suitable substituted / unsaturated R of B-R-9-BBN can be utilized to produce dienes, enynes, allenes etc. with defined stereochemistry. 9-BBN’s derivatives have been elegantly used for the asymmetric reduction of ketone moiety. Diels-Alder and Suzuki reactions have expanded the utility of 9-BBN for the synthesis of a variety of organic compounds required for industry. Consequently, this vast field in the form of a book will be helpful to synthetic organic chemists for easy access to literature, required for chemical transformations.
Ranjit S. Dhillon
Hydroboration and Organic Synthesis
9-Borabicyclo [3.3.1] nonane (9-BBN)
Hydroboration and Organic Synthesis
9-Borabicyclo [3.3.1] nonane (9-BBN)
语言 英语 ● 格式 PDF ● 网页 586 ● ISBN 9783540490760 ● 文件大小 21.3 MB ● 出版者 Springer Berlin ● 市 Heidelberg ● 国家 DE ● 发布时间 2007 ● 下载 24 个月 ● 货币 EUR ● ID 2162620 ● 复制保护 社会DRM